基于BS值的钢中多相组织分相技术

为了对钢中双相或多相组织进行分相定量表征，利用场发射扫描电镜(FE SEM)与电子背散射衍射技术(EBSD)中的BS值对其进行了详细的研究与讨论。结果表明，对于单相的铁素体、贝氏体或马氏体，其BS灰度分布图呈近似的正态分布，BS图可以呈现出类似于组织的图像。利用BS值可以很好地对结构相近的双相或多相组织进行分相定量。在分相定量时，需选择适合的拟合函数，定量结果才更为准确。     

Maximization of quadruple phase boundary for alkaline membrane fuel cell using non-stoichiometric α-MnO2 as cathode catalyst

Oxygen can only be reduced at the quadruple phase boundary (catalyst, carbon support, ionomer and oxygen) of the cathode catalyst layer with non-conducting electrocatalyst. To maximize the quadruple phase boundary sites is crucial to increase the peak power density of each membrane electrode assembly. The quadruple phase boundary is depending on the ratio of catalyst, carbon support and ionomer. The loading of catalyst layer is also crucial to the fuel cell performance. In this study, non-stoichiometric α-MnO₂ manganese dioxide nanorod material has been synthesized and the ratios of carbon, ionomer and catalyst loadings were optimized in alkaline membrane fuel cell. In total, ten membrane electrode assemblies have been manufactured and tested. Taguchi design method has been applied in order to understand the effect of each parameter. The conclusion finds out the ionomer has more influence on the alkaline membrane fuel cell peak power performance than carbon and loading.     

Structural transformation in Mn-substituted Sr2Bi2Ta2TiO12 Aurivillius phase synthesized by hydrothermal method: A comparative study and dielectric properties

In this study, a hydrothermal method was applied to synthesize the three-layer Aurivillius phase Sr₂Bi₂Ta₂TiO₁₂ (SBTTO) and Mn-substituted Sr_1·5Bi_2·5Ta₂Ti_0·5Mn_0·5O₁₂ (SBTTMO), with the use of NaOH as a mineralizer. The crystal structure, morphology, dielectric properties, and the correlation between the structural transformation and dielectric properties were investigated. The XRD data reveal that the SBTTO sample adopts a tetragonal crystal structure with the I4/mmm space group and is then transformed into an orthorhombic structure with the B2cb space group for SBTTMO. The morphology of both samples was observed by SEM, which showed anisotropic plate-like grains. With the Mn substitution, the ferroelectric transition temperature (T_c) significantly increases as the influence of the 6s² lone pair of Bi³⁺ increases, and this in turn further induces the relaxor-ferroelectric behavior. Consequently, the increase in T_c confirms the structural transformation from the paraelectric-tetragonal to the ferroelectric-orthorhombic phase.     

Ultrahigh and field-independent energy storage efficiency of (1-x)(Ba0.85Ca0.15)(Zr0.1Ti0.9)O3-xBi(Mg0.5Ti0.5)O3 ceramics

Relaxor ferroelectrics are attracting an increasing interest in the application of pulse power systems due to their excellent energy storage performance. In this paper, the (1-x)(Ba_0·85Ca_0.15)(Zr_0·1Ti_0.9)O₃-xBi(Mg_0·5Ti_0.5)O₃ ((1-x)BCZT-xBMT, x ≤ 0.2) relaxor ceramics are prepared by the solid state method. The influence of BMT on the microstructure, dielectric and energy storage properties of the prepared ceramics is investigated. The XRD results show that the peak intensity of impurities (Bi₂O₃, TiO₂ and Ba₂Bi₄Ti₅O₁₈) is gradually stronger than that of BCZT phase with x increasing. Meanwhile, the grain size of (1-x)BCZT-xBMT ceramics gradually increases on account of the appearance of impurities Bi₂O₃. Influenced by the impurities and BMT, the dielectric constant of prepared ceramics gradually decreases with x increasing. A large W_rec value of 0.65 J/cm³ with an ultrahigh η value of 97.89% is achieved at x = 0.15 due to the high breakdown strength and slim P-E hysteresis loop. Meanwhile, the η is insensitive to the electric field. The ultrahigh η leads to lesser energy loss during the charge and discharge process. It makes the 0.85BCZT-0.15BMT ceramic more attractive in the application of pulse power systems.     

Influence of the stoichiometry,microstructure, and metallization method on the dielectric properties of 0.94 Na0.5Bi0.5TiO3-0.06 BaTiO3

The morphotropic composition of the lead-free solid solution between Na_0.5Bi_0.5TiO₃ and BaTiO₃ (0.94 Na_0.5Bi_0.5TiO₃-0.06 BaTiO₃ or NBT-6BT) is of particular interest for the next generation of high-temperature capacitors but remains plagued by the diversity of dielectric properties reported in the literature. In order to explain the apparent inconsistencies among the reported dielectric properties of NBT-6BT, we examine the influence of stoichiometry, phase separation, and metallization method. We show that the nominal stoichiometry has a crucial effect, since increasing the nominal Na/Bi ratio increases conductivity and dielectric losses (tan δ). It also increases the real part of the permittivity (ε’) and the frequency dispersion of both ε’ and tan δ, thereby altering the shape of the evolution with temperature of the dielectric properties. Moreover it increases the depolarization temperature (T_d) and decreases the temperature of maximum permittivity (T_m). Phase separation also occurs during the synthesis of NBT-6BT as Na evaporation leads to the formation of secondary Ba-containing phases. We report that these phases can have a positive impact on the dielectric properties: a moderate volume fraction (2.5 to 3.0%) and average grain surface (0.9 to 3.0 µm²) of these secondary Ba-containing phases increase the relative permittivity, decrease the dielectric losses, and increase the insulation resistance. We also show that the metallization method impacts the dielectric properties and therefore may contribute to the differences between various reports. The dielectric properties of NBT-6BT samples are measured during successive heating/cooling cycles and reveal that the permittivity value is lower during the first heating when silver paste, even cured, is used. These three components contribute to explaining the diversity of the reported dielectric properties of NBT-6BT.     

Development of vibration damping materials based on butyl rubber: A study of the phase equilibrium,rheological, and dynamic properties of compositions

A detailed study of butyl rubber-based vibration damping formulations linking their composition, morphology, phase structure, viscosity, mechanical loss factor, and other characteristics is presented for the first time. High performance of the compositions including aromatic petroleum oil is explained by limited solubility of the plasticizer that leads to the formation of a highly-viscous emulsion (η_20°C ≈ 1000 Pa·s) consisting of a swollen butyl rubber matrix and dispersed oil droplets in the broad composition range. Chalk is found to be the best inorganic filler as its spherical particles provide strong adhesion to the reinforcing layer of aluminum foil. Aiming to eliminate ecologically unfriendly aromatic compounds, a new low-cost binding agent formulation based on butyl rubber mixed with polyisobutylene and highly refined mineral oil is suggested. Being environmentally safe, it possesses high viscosity of 1000–3000 Pa·s, cohesion strength of 3.5–5.0 N/cm, penetration of 4.5–6.0 mm, and mechanical loss factor up to 0.34 at room temperature, which are as good as, or even better than, the properties of currently produced vibration damping materials containing aromatic compounds. New materials can be used in car and aircraft parts for effective vibration isolation.     

Composition and structure of arsenic–antimony alloy electrodeposited from acidic chloride solution

AsSb alloy (0.70–95.81 wt.% As) was prepared by electrodeposition in As(III) and Sb(III) contained electrolytes. The influence of electrolyte composition, hydrochloric acid concentration, and temperature on the composition and structure of AsSb deposits was studied. The electroreduction mechanism of As(III) and Sb(III) in hydrochloric acid solution was revealed via thermodynamic analysis. The results show that the increase of H⁺ concentration promotes the reduction of As(III), while the increase of Cl⁻ concentration significantly inhibits the reduction of Sb(III). As a result, the As content in deposits increases gradually with the increase of hydrochloric acid concentration. Simultaneously, the phase structure of AsSb deposits evolves from crystalline to amorphous. When the As content is 24.55–33.75 wt.%, AsSb mixed crystal is obtained. The electrolysis temperature has little effect on the deposits composition, but the structure of deposits evolves from crystalline to amorphous with decreasing the temperature.     

Thermal stability of the nanolayered Fe2AlB2 in nitrogen and argon atmospheres

The thermal stability and decomposition mechanisms of Fe₂AlB₂ powders, synthesized by reactive powder metallurgy, were studied under nitrogen (N₂) or argon (Ar) atmospheres. The effects of using different FeB precursors to synthesize the Fe₂AlB₂ and hydrochloric acid (HCl) purification treatments on the thermal stability were also investigated. When as-synthesized Fe₂AlB₂ powders are treated in dilute HCl to dissolve impurity phases, decomposition in N₂ atmospheres occurs readily above 1200 K. The decomposition reaction involves β-FeB precipitation and the liberated Al atoms reacting with the ambient N₂ to form AlN. Under Ar environments, HCl-treated Fe₂AlB₂ powders decompose and precipitate β-FeB, by the out-diffusion of Al from the nanolaminated structure. Interestingly, isothermal annealing under N₂ atmospheres revealed that Fe₂AlB₂ was more thermally stable when synthesized from lab-synthesized, instead of commercially available, FeB precursors and when the HCl treatment was avoided. The effects of the various factors on the decomposition temperature and decomposition mechanisms are discussed herein.